Your Majesty, Your Royal Highnesses,
Ladies and Gentlemen.
At its meeting on the 11th November the Royal
Academy of Sciences decided to award the Nobel Prize for Physics for the year
1913 to Dr. Heike Kamerlingh Onnes, Professor at the University of Leyden "for
his investigations on the properties of matter at low temperatures which led,
inter alia, to the production of liquid helium".
As early as 100 years
ago research into the behaviour of gases at various pressures and temperatures
gave a great impetus to physics. Since this time the study of the connection
between the pressure, the volume and the temperature of gases has played a very
important part in physics, and particularly in thermodynamics - one of the most
important disciplines of modern physics.
In the years 1873 and 1880 Van
der Waals presented his famous laws governing gases which, owing to their great
importance for thermodynamics, were rewarded by the Royal Academy of Sciences in
1910 with the
Nobel Prize for Physics.
The thermodynamic laws of Van der Waals were
laid down on atheoretical basis under the assumption that certain properties
could be attributed to molecules and molecular forces. In the case of gases the
properties of which are changed by pressure and temperature, or in one way or
another do not agree with Van der Waals' hypothesis, deviations from these laws
occur.
A systematic experimental study of these deviations and the
changes they undergo due to temperature and the molecular structure of the gas
must therefore contribute greatly to our knowledge of the properties of the
molecules and of the phenomena associated with them.
It was for this
research that Kamerlingh Onnes set up his famous laboratory at the beginning of
the 1880's, and in it he designed and improved, with unusual success, the
physical apparatus needed for his experiments.
It is impossible to report
briefly here on the many important results of this work. They embrace the
thermodynamic properties at low temperatures of a series of monatomic and
diatomic gases and their mixtures, and have contributed to the development of
modern thermodynamics and to an elucidation of those associated phenomena which
are so difficult to explain. They have also made very important contributions to
our knowledge of the structure of matter and of phenomena related to
it.
Whilst important on its own account, this research has gained greater
significance because it has led to the attainment of the lowest temperatures so
far reached. These lie in the vicinity of so-called absolute zero, the lowest
temperature in thermodynamics.
The attainment of low temperatures in
general was not possible until we learnt to condense the so-called permanent
gases, which, since Faraday's pioneer work in this field in the middle of the
1820's, has been one of the most important tasks of thermodynamics.
After
Olszewski, Linde, and Hampson had prepared liquid oxygen and air in a variety of
ways, and after Dewar, having overcome great experimental difficulties, had
succeeded in condensing nitrogen, all temperatures down to -259°C, i.e. all
temperatures down to 14° from absolute zero, could be attained.
At these
low temperatures all known gases can easily be condensed, except for helium,
which was discovered in the atmosphere in the year 1895.
Thus, by
condensing this it would be possible to reach still lower temperatures. After
both Olszewski and Dewar, Travers, and Jacquerod had tried in vain to prepare
liquid helium, using a variety of met hods it was generally assumed that it was
impossible.
The question was solved in 1908, however, by Kamerlingh
Onnes, who then prepared liquid helium for the first time.
I should have
to cover too much ground if I were to report here on the experimental equipment
with which Kamerlingh Onnes was at last successful in liquefying helium, and on
the enormous experimental difficulties which had to be overcome. I would only
mention here that the liquefaction of helium represented a continuation of the
long series of investigations into the properties of gases and liquids at low
temperatures which Kamerlingh Onnes has carried out in so praiseworthy a manner.
These investigations finally led to the determination of the so-called isotherms
of helium and the knowledge gained here was the first step towards the
liquefaction of helium. Kamerlingh Onnes has constructed cold baths with liquid
helium which permit research to be done into the properties of substances at
temperatures which lie between 4,3° and 1,15° from absolute zero.
The
attainment of these low temperatures is of the greatest importance to physics
research, for at these temperatures both the properties of the substances and
also the course followed by physical phenomena, are generally quite different
from those at our normal and higher temperatures, and a knowledge of these
changes is of fundamental importance in answering many of the questions of
modern physics.
Let me mention one of these particularly
here.
Various principles borrowed from gas thermodynamics have been
transferred to the so-called theory of electrons, which is the guiding principle
in physics in explaining all electrical, magnetic, optical, and many heat
phenomena.
The laws which have been arrived at in this way also seem to
be confirmed by measurements at our normal and higher temperatures. That the
situation is at very low temperatures not the same, however, has, amongst other
things, been shown by Kamerlingh Onnes' experiments on resistance to electrical
conduction at helium temperatures and by the determinations which Nernst and his
students have carried out in relation to specific heat at liquid
temperatures.
It has become more and more clear that a change in the
whole theory of electrons is necessary. Theoretical work in this direction has
already been begun by a number of research workers, particularly by Planck and
Einstein.
In the meantime new supports had to be created for these
investigations. These could only be obtained by a continued experimental study
of the properties of substances at low temperatures, particularly at helium
temperatures, which are the most suitable for throwing light upon phenomena in
the world of electrons. Kamerlingh Onnes' merit lies in the fact that he has
created these possibilities and at the same time opened up a field of the
greatest consequence and significance to physical science.
Owing to the
great importance which Kamerlingh Onnes' work has been seen to have for research
in physics, the Royal Academy of Sciences has found ample grounds for bestowing
upon him the Nobel Prize for Physics for the year 1913.